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| Presentation | 2007-10-26 14:15 Adsorption Place Dependence of STM/STS in Endohedral Metallofullerene Er@C82 Molecule on Alkanethiol SAM Keijiro Kono, Norihiro Kobayashi, Masachika Iwamoto, Yuhsuke Yasutake (Tokyo Tech.), Shingo Okubo, Toshiya Okazaki (AIST), Yutaka Majima (Tokyo Tech.)  OME2007-44 Link to ES Tech. Rep. Archives: OME2007-44 |
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| Abstract | (in Japanese) | (See Japanese page) |
| (in English) | We report adsorption place dependence of endohedral metallofullerene Er@C82 on alkanethiol self-assembled monolayer (SAM) by scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS) to realize liquid N2 temperature operation of single molecular orientation switch of the endohedral metallofullerene. From dI/dV curves, same peak position and gap width were observed on Er@C82 on step edge and terras of octanethiol SAM, but on etch pit or boundary, gap width was wider and narrower, respectively. On the basis of the energy diagram, we have evaluated the HOMO-LUMO gap of Er@C82 as 0.5 eV on step edge and terras, and the Fermi level found to be located on 0.1 eV above the HOMO level. | |
| Keyword | (in Japanese) | (See Japanese page) |
| (in English) | Endohedral Metallofullerene / Alkanethiol SAM / HOMO-LUMO gap / Molecular Nanoelectronics / / / / | |
| Reference Info. | IEICE Tech. Rep., vol. 107, no. 292, OME2007-44, pp. 7-12, Oct. 2007. | |
| Paper # | OME2007-44 | |
| Date of Issue | 2007-10-19 (OME) | |
| ISSN | Print edition: ISSN 0913-5685 Online edition: ISSN 2432-6380 | |
| Copyright and reproduction |
All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034) | |
| Download PDF | OME2007-44 Link to ES Tech. Rep. Archives: OME2007-44 |
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| Conference Information | |
| Committee | OME |
| Conference Date | 2007-10-26 - 2007-10-26 |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | Kikai-Shinko-Kaikan Bldg. |
| Topics (in Japanese) | (See Japanese page) |
| Topics (in English) | |
| Paper Information | |
| Registration To | OME |
| Conference Code | 2007-10-OME |
| Language | Japanese |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Adsorption Place Dependence of STM/STS in Endohedral Metallofullerene Er@C82 Molecule on Alkanethiol SAM |
| Sub Title (in English) | |
| Keyword(1) | Endohedral Metallofullerene |
| Keyword(2) | Alkanethiol SAM |
| Keyword(3) | HOMO-LUMO gap |
| Keyword(4) | Molecular Nanoelectronics |
| Keyword(5) | |
| Keyword(6) | |
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| Keyword(8) | |
| 1st Author's Name | Keijiro Kono |
| 1st Author's Affiliation | Tokyo Institute of Technology (Tokyo Tech.) |
| 2nd Author's Name | Norihiro Kobayashi |
| 2nd Author's Affiliation | Tokyo Institute of Technology (Tokyo Tech.) |
| 3rd Author's Name | Masachika Iwamoto |
| 3rd Author's Affiliation | Tokyo Institute of Technology (Tokyo Tech.) |
| 4th Author's Name | Yuhsuke Yasutake |
| 4th Author's Affiliation | Tokyo Institute of Technology (Tokyo Tech.) |
| 5th Author's Name | Shingo Okubo |
| 5th Author's Affiliation | Advanced Industrial Science and Technology (AIST) |
| 6th Author's Name | Toshiya Okazaki |
| 6th Author's Affiliation | Advanced Industrial Science and Technology (AIST) |
| 7th Author's Name | Yutaka Majima |
| 7th Author's Affiliation | Tokyo Institute of Technology (Tokyo Tech.) |
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| Speaker | Author-1 |
| Date Time | 2007-10-26 14:15:00 |
| Presentation Time | 30 minutes |
| Registration for | OME |
| Paper # | OME2007-44 |
| Volume (vol) | vol.107 |
| Number (no) | no.292 |
| Page | pp.7-12 |
| #Pages | 6 |
| Date of Issue | 2007-10-19 (OME) |
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