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Paper Abstract and Keywords
Presentation 2009-08-11 11:15
Effectiveness of New Deposition Method for Barrier Metal Applicable to Through Silicon Via -- Properties of ZrNx Film Formed at Low Temperature --
Masaru Sato, Mayumi B. Takeyama (Kitami Inst. of Tech.), Yuichiro Hayasaka, Eiji Aoyagi (Tohoku Univ.), Atsushi Noya (Kitami Inst. of Tech.) CPM2009-44 Link to ES Tech. Rep. Archives: CPM2009-44
Abstract (in Japanese) (See Japanese page) 
(in English) A low process temperature as low as 200°C is one of the most important requirements for the metallization technology of the three-dimensional integration with through Si via (TSV). In the present study, we propose a new deposition method for preparing a thin nitride diffusion barrier applicable to TSV technology, in which sputtering of metal and following
nitridation by radical species are combined. By means of this procedure, we can prepare a 5-nm thick ZrN film without substrate heating at temperature below 200°C. This film tolerated annealing at 500°C as a barrier without any interfacial layers formation, which performance is comparable to that of ZrN formed by reactive-sputtering. It is revealed that the proposed method is probably the unique method satisfying the requirements for TSV processes.
Keyword (in Japanese) (See Japanese page) 
(in English) Si-ULSI / through Si via / ZrN, / nitridation / diffusion barrier / low process temperature / /  
Reference Info. IEICE Tech. Rep., vol. 109, no. 171, CPM2009-44, pp. 57-60, Aug. 2009.
Paper # CPM2009-44 
Date of Issue 2009-08-03 (CPM) 
ISSN Print edition: ISSN 0913-5685    Online edition: ISSN 2432-6380
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All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034)
Download PDF CPM2009-44 Link to ES Tech. Rep. Archives: CPM2009-44

Conference Information
Committee CPM  
Conference Date 2009-08-10 - 2009-08-11 
Place (in Japanese) (See Japanese page) 
Place (in English) Hirosaki Univ. 
Topics (in Japanese) (See Japanese page) 
Topics (in English) Electronic Component Parts and Materials, etc. 
Paper Information
Registration To CPM 
Conference Code 2009-08-CPM 
Language Japanese 
Title (in Japanese) (See Japanese page) 
Sub Title (in Japanese) (See Japanese page) 
Title (in English) Effectiveness of New Deposition Method for Barrier Metal Applicable to Through Silicon Via 
Sub Title (in English) Properties of ZrNx Film Formed at Low Temperature 
Keyword(1) Si-ULSI  
Keyword(2) through Si via  
Keyword(3) ZrN,  
Keyword(4) nitridation  
Keyword(5) diffusion barrier  
Keyword(6) low process temperature  
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Keyword(8)  
1st Author's Name Masaru Sato  
1st Author's Affiliation Kitami Institute of Technology (Kitami Inst. of Tech.)
2nd Author's Name Mayumi B. Takeyama  
2nd Author's Affiliation Kitami Institute of Technology (Kitami Inst. of Tech.)
3rd Author's Name Yuichiro Hayasaka  
3rd Author's Affiliation Tohoku University (Tohoku Univ.)
4th Author's Name Eiji Aoyagi  
4th Author's Affiliation Tohoku University (Tohoku Univ.)
5th Author's Name Atsushi Noya  
5th Author's Affiliation Kitami Institute of Technology (Kitami Inst. of Tech.)
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Speaker Author-1 
Date Time 2009-08-11 11:15:00 
Presentation Time 25 minutes 
Registration for CPM 
Paper # CPM2009-44 
Volume (vol) vol.109 
Number (no) no.171 
Page pp.57-60 
#Pages
Date of Issue 2009-08-03 (CPM) 


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