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Paper Abstract and Keywords
Presentation 2022-03-26 13:50
Ammonia electrosynthesis at low temperatures and atmospheric pressure using Ru/TiO2/CP electrode prepared by electrodeposition
Ryuto Konno, Hidenobu Shiroishi (NIT, Tokyo College), Mika Shiraishi, Mikka Nishitani-Gamo (Toyo Univ.) OME2021-67
Abstract (in Japanese) (See Japanese page) 
(in English) The development of a highly active electrochemical nitrogen reduction catalyst for low temperatures and atmospheric pressure enables the use of ammonia generated from renewable energy on-site as a hydrogen carrier. In this study, Ru/TiO2/CP electrode were prepared by electrodepositing Ru nanoparticles on TiO2 nanoparticle-modified carbon paper. The electrochemical nitrogen reduction ability of the catalysts was evaluated using a fuel cell type electrolytic cell at low temperatures and atmospheric pressure. The crystallinity, particle size, and oxidation state of Ru nanoparticles were characterized by X-ray diffraction measurement, X-ray photoelectron spectroscopy, and transmission electron microscope. It was clarified that the amount of TiO2 had a great effect on the overpotential of the nitrogen reduction reaction, and the amount of ammonia increased about 2.5 times using a square wave with a hydrogen generation free potential compared to conventional potentiostatic electrolysis.
Keyword (in Japanese) (See Japanese page) 
(in English) ammonia / electrochemical nitrogen reduction / Ru electrodeposition / fuel cell type electrolytic cell / / / /  
Reference Info. IEICE Tech. Rep., vol. 121, no. 441, OME2021-67, pp. 5-8, March 2022.
Paper # OME2021-67 
Date of Issue 2022-03-19 (OME) 
ISSN Online edition: ISSN 2432-6380
Copyright
and
reproduction
All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034)
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Conference Information
Committee OME  
Conference Date 2022-03-26 - 2022-03-26 
Place (in Japanese) (See Japanese page) 
Place (in English) Seikei Univ, 
Topics (in Japanese) (See Japanese page) 
Topics (in English) battery, electrochemistry, surface modification, catalyst, in situ observation, capacitor 
Paper Information
Registration To OME 
Conference Code 2022-03-OME 
Language Japanese 
Title (in Japanese) (See Japanese page) 
Sub Title (in Japanese) (See Japanese page) 
Title (in English) Ammonia electrosynthesis at low temperatures and atmospheric pressure using Ru/TiO2/CP electrode prepared by electrodeposition 
Sub Title (in English)  
Keyword(1) ammonia  
Keyword(2) electrochemical nitrogen reduction  
Keyword(3) Ru electrodeposition  
Keyword(4) fuel cell type electrolytic cell  
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1st Author's Name Ryuto Konno  
1st Author's Affiliation National Institute of Technology, Tokyo College (NIT, Tokyo College)
2nd Author's Name Hidenobu Shiroishi  
2nd Author's Affiliation National Institute of Technology, Tokyo College (NIT, Tokyo College)
3rd Author's Name Mika Shiraishi  
3rd Author's Affiliation Toyo University (Toyo Univ.)
4th Author's Name Mikka Nishitani-Gamo  
4th Author's Affiliation Toyo University (Toyo Univ.)
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Speaker Author-1 
Date Time 2022-03-26 13:50:00 
Presentation Time 15 minutes 
Registration for OME 
Paper # OME2021-67 
Volume (vol) vol.121 
Number (no) no.441 
Page pp.5-8 
#Pages
Date of Issue 2022-03-19 (OME) 


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