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Presentation 2013-05-16 13:50
Vapor deposition of low-molecular-weight PEDOT and its doping characteristics
Taikai Eguchi, Ai Hasegawa, Kousuke Tsuchiya, Kuniaki Tanaka, Kenji Ogino, Hiroaki Usui (Tokyo Univ. of Agriculture and Tech.) OME2013-24 Link to ES Tech. Rep. Archives: OME2013-24
Abstract (in Japanese) (See Japanese page) 
(in English) Poly (3,4-ethylenedioxythiophene) (PEDOT) is one of the well-known conductive polymers that has excellent thermal stability and high conductivity. However, it is difficult to prepare thin films of PEDOT by itself. The common method of film formation is to use a composite of PEDOT with polystyrene sulfonate (PSS) to form water dispersion that can be deposited by wet-coating methods. However, the high acidity of PSS is known to cause such disadvantage as corrosion of devices. In this paper, low-molecular weight PEDOT was synthesized and its thin films were prepared by physical vapor deposition. The deposited films were optically characterized by IR spectra and UV-Vis spectra and electrically characterized by current-voltage measurement. It was found that deposited PEDOT film had good optical transparency, and its electrical conductivity was about 10-8 S cm-1. Deposited PEDOT film has been subjected to thermal annealing, which improved resistance of the films against organic solvents and also increased the electrical conductivity by 10 to 100 times. The deposited film was exposed to I2-vapor for doping, which increased the conductivity of the film to 1 S cm-1.
Keyword (in Japanese) (See Japanese page) 
(in English) PEDOT / conductive polymer / vapor deposition / doping / / / /  
Reference Info. IEICE Tech. Rep., vol. 113, no. 42, OME2013-24, pp. 7-12, May 2013.
Paper # OME2013-24 
Date of Issue 2013-05-09 (OME) 
ISSN Print edition: ISSN 0913-5685    Online edition: ISSN 2432-6380
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Download PDF OME2013-24 Link to ES Tech. Rep. Archives: OME2013-24

Conference Information
Committee OME  
Conference Date 2013-05-16 - 2013-05-16 
Place (in Japanese) (See Japanese page) 
Place (in English) Kikai-Shinko-Kaikan Bldg. 
Topics (in Japanese) (See Japanese page) 
Topics (in English) Fabrication, Characterization and General Aspects Related to Organic Materials 
Paper Information
Registration To OME 
Conference Code 2013-05-OME 
Language Japanese 
Title (in Japanese) (See Japanese page) 
Sub Title (in Japanese) (See Japanese page) 
Title (in English) Vapor deposition of low-molecular-weight PEDOT and its doping characteristics 
Sub Title (in English)  
Keyword(1) PEDOT  
Keyword(2) conductive polymer  
Keyword(3) vapor deposition  
Keyword(4) doping  
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1st Author's Name Taikai Eguchi  
1st Author's Affiliation Tokyo University of Agriculture and Technology (Tokyo Univ. of Agriculture and Tech.)
2nd Author's Name Ai Hasegawa  
2nd Author's Affiliation Tokyo University of Agriculture and Technology (Tokyo Univ. of Agriculture and Tech.)
3rd Author's Name Kousuke Tsuchiya  
3rd Author's Affiliation Tokyo University of Agriculture and Technology (Tokyo Univ. of Agriculture and Tech.)
4th Author's Name Kuniaki Tanaka  
4th Author's Affiliation Tokyo University of Agriculture and Technology (Tokyo Univ. of Agriculture and Tech.)
5th Author's Name Kenji Ogino  
5th Author's Affiliation Tokyo University of Agriculture and Technology (Tokyo Univ. of Agriculture and Tech.)
6th Author's Name Hiroaki Usui  
6th Author's Affiliation Tokyo University of Agriculture and Technology (Tokyo Univ. of Agriculture and Tech.)
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Speaker Author-2 
Date Time 2013-05-16 13:50:00 
Presentation Time 20 minutes 
Registration for OME 
Paper # OME2013-24 
Volume (vol) vol.113 
Number (no) no.42 
Page pp.7-12 
#Pages
Date of Issue 2013-05-09 (OME) 


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