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Paper Abstract and Keywords
Presentation 2013-12-27 13:45
Synthesis and Dynamic Design of Structured Soft Material Derived from Metal Complexes
Takashi Arimura, Masaru Mukai (AIST), Naoki Mitsuyama, Shogo Ikeda, Nobuyoshi Miyamoto (FIT) OME2013-87
Abstract (in Japanese) (See Japanese page) 
(in English) Self-organization could cover structural and dynamic order of both equilibrium structure and non-equilibrium, incorporating nonlinear chemical processes and energy flow concerning dissipative structure. One dissipative structure that exhibits temporal and spatiotemporal oscillation is known to be chemically generated by the famous Belousov-Zhabotinsky (BX) reaction. Rhythmic oscillation of the Ruthenium porphyrin solution by BZ reaction was demonstrated without any on-off switching of external stimuli for the first time. The reaction was performed in the presence of bromate ion, malonic acid, and the metal catalyst in sulfuric acid solution. In the course of the reaction, the oscillating waveform of the Ruthenium porphyrin was affected by the concentration of the components, especially the metal catalyst. When the solution was homogeneously stirred at room temperature, the color of the solution periodically changed every 5 min. based on the redox changes of the porphyrin.
Keyword (in Japanese) (See Japanese page) 
(in English) Self-organization / porphyrin / Redox potential / Self-oscillation / Belousov-Zhabotinsky reaction / Dissipative structure / Actuator /  
Reference Info. IEICE Tech. Rep., vol. 113, no. 375, OME2013-87, pp. 5-8, Dec. 2013.
Paper # OME2013-87 
Date of Issue 2013-12-20 (OME) 
ISSN Print edition: ISSN 0913-5685    Online edition: ISSN 2432-6380
Copyright
and
reproduction		 All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034)
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Conference Information
Committee OME  
Conference Date 2013-12-27 - 2013-12-27 
Place (in Japanese) (See Japanese page) 
Place (in English) Miyako Marine Terminal 
Topics (in Japanese) (See Japanese page) 
Topics (in English) Biotechnology 
Paper Information
Registration To OME 
Conference Code 2013-12-OME 
Language Japanese 
Title (in Japanese) (See Japanese page) 
Sub Title (in Japanese) (See Japanese page) 
Title (in English) Synthesis and Dynamic Design of Structured Soft Material Derived from Metal Complexes 
Sub Title (in English)  
Keyword(1) Self-organization  
Keyword(2) porphyrin  
Keyword(3) Redox potential  
Keyword(4) Self-oscillation  
Keyword(5) Belousov-Zhabotinsky reaction  
Keyword(6) Dissipative structure  
Keyword(7) Actuator  
Keyword(8)  
1st Author's Name Takashi Arimura  
1st Author's Affiliation National Institute of Advanced Industrial Science and Technology (AIST)
2nd Author's Name Masaru Mukai  
2nd Author's Affiliation National Institute of Advanced Industrial Science and Technology (AIST)
3rd Author's Name Naoki Mitsuyama  
3rd Author's Affiliation Fukuoka Institute of Technology (FIT)
4th Author's Name Shogo Ikeda  
4th Author's Affiliation Fukuoka Institute of Technology (FIT)
5th Author's Name Nobuyoshi Miyamoto  
5th Author's Affiliation Fukuoka Institute of Technology (FIT)
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Speaker Author-1 
Date Time 2013-12-27 13:45:00 
Presentation Time 25 minutes 
Registration for OME 
Paper # OME2013-87 
Volume (vol) vol.113 
Number (no) no.375 
Page pp.5-8 
#Pages 4 
Date of Issue 2013-12-20 (OME) 

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