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Paper Abstract and Keywords
Presentation 2014-11-29 11:30
[Invited Talk] Control of Organic/Inorganic Interface by Self-Assembled Monolayer having Reactive Terminal Group
Hiroaki Usui (Tokyo Univ. Agricul. & Tech.) OME2014-64
Abstract (in Japanese) (See Japanese page) 
(in English) Interface between inorganic substrate and organic layer involves essential problems due to inconsistency in physical and chemical nature of organic and inorganic materials. This paper reviews our strategy of solving this problem by formig chemical bonds at the interface via a self-assembled monolayer (SAM) that has reactive terminal group. Surface-tethered polypeptide film can be obtained by depositing aminoacid N-carboxy anhydride on amino-terminated SAM. SAMs having azo or benzophenone terminals are utilized to grown variety of vinyl polymers. It is also possible to tether a spin-coated polymer to an inorganic substrate via a reactive SAM. These methods produce polymer thin films that are tightly anchored to the inorganic substrates. It was observed that this method can lead to a marked improvement in adhesion strength of the organic layer, microstructure, and charge injection from the inorganic electrode to the organic layer.
Keyword (in Japanese) (See Japanese page) 
(in English) Interface control / Self-assembled monolayer / Deposition polymerization / Adhesion strength / Charge injection / SAM / OLED /  
Reference Info. IEICE Tech. Rep., vol. 114, no. 341, OME2014-64, pp. 25-30, Nov. 2014.
Paper # OME2014-64 
Date of Issue 2014-11-21 (OME) 
ISSN Print edition: ISSN 0913-5685    Online edition: ISSN 2432-6380
Copyright
and
reproduction		 All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034)
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Conference Information
Committee OME  
Conference Date 2014-11-28 - 2014-11-29 
Place (in Japanese) (See Japanese page) 
Place (in English) Amamiooshima Chamber of Commerce and Industry 
Topics (in Japanese) (See Japanese page) 
Topics (in English) biotechnology, interfacial phenomena, etc. 
Paper Information
Registration To OME 
Conference Code 2014-11-OME 
Language Japanese 
Title (in Japanese) (See Japanese page) 
Sub Title (in Japanese) (See Japanese page) 
Title (in English) Control of Organic/Inorganic Interface by Self-Assembled Monolayer having Reactive Terminal Group 
Sub Title (in English)  
Keyword(1) Interface control  
Keyword(2) Self-assembled monolayer  
Keyword(3) Deposition polymerization  
Keyword(4) Adhesion strength  
Keyword(5) Charge injection  
Keyword(6) SAM  
Keyword(7) OLED  
Keyword(8)  
1st Author's Name Hiroaki Usui  
1st Author's Affiliation Tokyo University of Agriculture and Technology (Tokyo Univ. Agricul. & Tech.)
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Speaker Author-1 
Date Time 2014-11-29 11:30:00 
Presentation Time 35 minutes 
Registration for OME 
Paper # OME2014-64 
Volume (vol) vol.114 
Number (no) no.341 
Page pp.25-30 
#Pages 6 
Date of Issue 2014-11-21 (OME) 

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