| Paper Abstract and Keywords |
| Presentation |
2026-01-26 15:40
Time-resolved FT-IR observation of polyurea polymerization and hydrogen bonding process within one second Yasuko Koshiba, Satoshi Atsumi, Azumi Akiyama, Shohei Horike, Masahiro Funahashi (Kobe Univ.), Kenji Ishida (Kyushu Univ..) OME2025-57 |
| Abstract |
(in Japanese) |
(See Japanese page) |
| (in English) |
Polyurea and its derivatives exhibit excellent physical and chemical properties owing to intermolecular hydrogen bonding. In this study, polyurea formation via the polyaddition reaction between diamines and diisocyanates was investigated in situ using fast time-resolved Fourier-transform infrared attenuated total reflectance (FTIR–ATR) spectroscopy, enabling analysis of the reaction within 1 s. Polyurea was polymerized on an ATR prism using aliphatic and cycloaliphatic diamines and diisocyanates under rapid-scan FT-IR measurements, allowing kinetic analysis based on changes in the ATR spectra. Furthermore, spectral analysis focusing on intermolecular hydrogen bond formation revealed differences in hydrogen-bonding behavior arising from variations in molecular structure. |
| Keyword |
(in Japanese) |
(See Japanese page) |
| (in English) |
polyurea / time-resolved FT-IR / intermolecular hydrogen bonding / reaction kinetics / / / / |
| Reference Info. |
IEICE Tech. Rep., vol. 125, no. 337, OME2025-57, pp. 27-32, Jan. 2026. |
| Paper # |
OME2025-57 |
| Date of Issue |
2026-01-19 (OME) |
| ISSN |
Online edition: ISSN 2432-6380 |
Copyright and reproduction |
All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034) |
| Download PDF |
OME2025-57 |
| Conference Information |
| Committee |
OME |
| Conference Date |
2026-01-26 - 2026-01-26 |
| Place (in Japanese) |
(See Japanese page) |
| Place (in English) |
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| Topics (in Japanese) |
(See Japanese page) |
| Topics (in English) |
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| Paper Information |
| Registration To |
OME |
| Conference Code |
2026-01-OME |
| Language |
Japanese |
| Title (in Japanese) |
(See Japanese page) |
| Sub Title (in Japanese) |
(See Japanese page) |
| Title (in English) |
Time-resolved FT-IR observation of polyurea polymerization and hydrogen bonding process within one second |
| Sub Title (in English) |
|
| Keyword(1) |
polyurea |
| Keyword(2) |
time-resolved FT-IR |
| Keyword(3) |
intermolecular hydrogen bonding |
| Keyword(4) |
reaction kinetics |
| Keyword(5) |
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| 1st Author's Name |
Yasuko Koshiba |
| 1st Author's Affiliation |
KobeUniversity (Kobe Univ.) |
| 2nd Author's Name |
Satoshi Atsumi |
| 2nd Author's Affiliation |
KobeUniversity (Kobe Univ.) |
| 3rd Author's Name |
Azumi Akiyama |
| 3rd Author's Affiliation |
KobeUniversity (Kobe Univ.) |
| 4th Author's Name |
Shohei Horike |
| 4th Author's Affiliation |
KobeUniversity (Kobe Univ.) |
| 5th Author's Name |
Masahiro Funahashi |
| 5th Author's Affiliation |
KobeUniversity (Kobe Univ.) |
| 6th Author's Name |
Kenji Ishida |
| 6th Author's Affiliation |
Kyushu University (Kyushu Univ..) |
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| Speaker |
Author-1 |
| Date Time |
2026-01-26 15:40:00 |
| Presentation Time |
25 minutes |
| Registration for |
OME |
| Paper # |
OME2025-57 |
| Volume (vol) |
vol.125 |
| Number (no) |
no.337 |
| Page |
pp.27-32 |
| #Pages |
6 |
| Date of Issue |
2026-01-19 (OME) |