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Paper Abstract and Keywords
Presentation 2016-03-03 14:20
[Invited Talk] Novel Design and Organic Device Applications of n-Type Semiconducting Polymers
Tsuyoshi Michinobu (Tokyo Tech) OME2015-88
Abstract (in Japanese) (See Japanese page) 
(in English) Novel n-type semiconducting polymers were developed and applied to various electronic devices. First, fullerene (C60) polymers were successfully synthesized by the azide-alkyne cycloaddition polymerization with a carefully designed comonomer. The resulting fullerene polymers showed n-type performances in the polymer memory characteristics. Secondly, a [2+2] cycloaddition-retroelectrocyclization of tetracyanoethylene (TCNE) was employed as a new postfunctionalization method of creating highly cyanated n-type semiconducting polymers. A change in the energy levels from p-type to n-type characters was demonstrated by the thin film transistor (TFT) performances. Lastly, benzobisthiadiazole (BBT)-based narrow band gap semiconducting polymers were synthesized by Pd-catalyzed polycondensation. Their charge polarity in TFTs could be controlled by the comonomer structures, heteroatom substitutions, and side chain engineering. Furthermore, fullerene-free polymer solar cells were fabricated by using the BBT-based n-type semiconducting polymers.
Keyword (in Japanese) (See Japanese page) 
(in English) Organic semiconducting polymer / thin film transistor / organic solar cell / organic memory / / / /  
Reference Info. IEICE Tech. Rep., vol. 115, no. 485, OME2015-88, pp. 11-14, March 2016.
Paper # OME2015-88 
Date of Issue 2016-02-25 (OME) 
ISSN Print edition: ISSN 0913-5685    Online edition: ISSN 2432-6380
Copyright
and
reproduction		 All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034)
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Conference Information
Committee OME  
Conference Date 2016-03-03 - 2016-03-03 
Place (in Japanese) (See Japanese page) 
Place (in English) S322 lecture room, Tokyo Tech, O-okayama campus 
Topics (in Japanese) (See Japanese page) 
Topics (in English) Organic devices and materials, etc. 
Paper Information
Registration To OME 
Conference Code 2016-03-OME 
Language Japanese 
Title (in Japanese) (See Japanese page) 
Sub Title (in Japanese) (See Japanese page) 
Title (in English) Novel Design and Organic Device Applications of n-Type Semiconducting Polymers 
Sub Title (in English)  
Keyword(1) Organic semiconducting polymer  
Keyword(2) thin film transistor  
Keyword(3) organic solar cell  
Keyword(4) organic memory  
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1st Author's Name Tsuyoshi Michinobu  
1st Author's Affiliation Tokyo Institute of Technology (Tokyo Tech)
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Speaker Author-1 
Date Time 2016-03-03 14:20:00 
Presentation Time 40 minutes 
Registration for OME 
Paper # OME2015-88 
Volume (vol) vol.115 
Number (no) no.485 
Page pp.11-14 
#Pages 4 
Date of Issue 2016-02-25 (OME) 

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